CAS No. 2687-12-9
Alias 3-chloro-1-phenylpropene; chlorinated cinnamyl; chlorinated cinnamene; 3-phenylallyl chloride; 3-chloro-1-phenyl-1-propene; cinnamyl chloride; Chloro-1-phenyl-2-propene; cinnamyl chloride.
Molecular formula C9H9Cl
Molecular weight 152.66
EINECS NO. 220-246-4
Appearance colorless to pale yellow liquid
Assay >97%
Melting point 19 °C
Boiling point 108 °C
Density 1.096 g/mL at 25 °C (lit.)
Refractive index n20/D: 1.584 (lit.)
Flash point 175 °F
Packing 200kg / plastic bucket
Beilstein 05, II, 372
Fieser 13,299
Specific Gravity 1.096
Solubility Soluble in water (0.2 g/L at 20°C).
Packing 200kg / plastic bucket
Applications
Cinnamyl chloride is used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.
Storage: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C
Solution: Cinnamyl chloride can be miscible with alcohol and ether, soluble in acetone, soluble in benzene, insoluble in water.
Production method: obtained by chloromethylation of styrene. Hydrochloric acid and formaldehyde were added to the reaction vessel, and styrene was added thereto with stirring, and the mixture was heated under reflux for 3 hours. After standing for 1 h, the lower layer of waste acid was separated, and the upper reaction liquid was dehydrated with anhydrous calcium chloride to obtain cinnamyl chloride.
Other names: 3-chloro-1-phenylpropene; chlorinated cinnamyl; chlorinated cinnamene; 3-phenylallyl chloride; 3-chloro-1-phenyl-1-propene; cinnamyl chloride; Chloro-1-phenyl-2-propene; cinnamyl chloride. CAS No.:2687-12-9 Molecular formula: C9H9Cl Molecular weight: 152.66 Molar mass: 152.621 Boiling point: 108 °C12 mm Hg(lit.) Flash point: 79.4±0.0 °C Refractive index: n20/D: 1.584 (lit.) Properties: Colorless to pale yellow liquid Purity: >97% Packaging: 200kg / plastic bucket Storage method: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C Usage: Used in fine chemicals and organic synthesis. It is commonly used in the synthesis of cardiovascular and cerebrovascular drugs, such as brain azine, cinnamylpiperazine and so on. It is also one of the important spices. it is used to produce other chemicals. For example, it can react with Acetoacetic acid ethyl ester to get 2-trans-Cinnamyl-acetoacetic acid ethyl ester. The reaction occurs with reagents potassium carbonate, acetone. It was also used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.
Cinnamyl Chloride(CAS:21087-29-6)
Product Name: Cinnamyl Chloride Alias: 3-chloro-1-phenylpropene; 3-phenylallyl chloride; 3-chloro-1-phenyl-1-propene; (3-chloroprop-1-en-1-yl)benzene; trans-Cinnamyl chloride CAS No.: 2687-12-9 EINECS NO.: 220-246-4 Molecular formula: C9H9Cl Molecular weight: 152.66 Appearance: colorless to pale yellow liquid Assay: >97% Melting point: 19 degrees Celsius Boiling point: 108 degrees Celsius Density: 1.096 g/mL at 25 degrees Celsius (lit.) Refractive index: n20/D: 1.584 (lit.) Flash point: 175 degrees Fahrenheit Packing: 200kg / plastic bucket Beilstein: 05, II, 372 Fieser: 13,299 Specific Gravity: 1.096 Solubility: Soluble in water (0.2 g/L at 20 degrees Celsius). Packing: 200kg / plastic bucket
Supplier: Cinnamic acid, cinnamaldehyde, cinnamon alcohol, methyl cinnamate, ethyl cinnamate, benzaldehyde, potassium cinnamate, isoamyl p methoxycinnamate, alpha methylcinnamic acid, sodium cinnamate, cinnamamide, benzyl cinnamate, propyl cinnamate, 2 methylcinnamic acid, 2 methoxycinnamic acid, 3 (trifluoromethyl)cinnamic acid, 2 bromocinnamic acid, 4 bromocinnamic acid, p hydroxycinnamic acid, 4 fluorocinnamic acid, 4 methoxycinnamic acid, phenethyl cinnamate, cinnamyl acetate, alpha methylcinnamaldehyde, cinnamyl chloride
Services: Export
Supplier: Cinnamic aldehyde, cinnamic alcohol, cinnamic acide, methylcinnamate, cinnamyl acetate, cinnamyl propionate, cinnamyl isovalerate, cinnamyl chloride, food additive
Buyer: Benzophenone
Cinnamic aldehyde M.F.: c9h8o Cas #: 104-55-2 M.W.: 132.16 Description: unique scent, light yellow liquid Assay(%):98 Specific gravity(25/25oc): 1.046-1.050 Refraction ratio(20oc): 1.619-1.623 Acidity(%): _1.0 Usage: used with hyacinthin, the necessity for concocting hyacinth essence, rose essence and etc; also it is an important medical material. Packing: 200kg/plastic drum
Cinnamic alcohol ItemSpecification M.F.C9h10o Structural formula Cas #104-54-1 M.W.134.18 AppearanceWhite to light yellow crystal or colorless to light yellow liquid Alcohol content (%)99 Freezing point (oc)33.0 Dissociated aldehyde content (%)_1.0 Solubility1g sample dissolves in 1ml 70% ethanol (v/v) completely UsageUsed with hyacinthin, the necessity for concocting hyacinth essence, rose essence and etc; also it is an important medical material. Packing25, 30, 200kg/plastic drum
First, flavor and fragrance Cinnamyl alcohol is mainly used in the formulation of apricot, peach, raspberry, plum and other flavors, cosmetics and soap flavors. It has a mild, long-lasting and comfortable aroma, elegant fragrance, and is also used as a fixative. Often shared with phenylacetaldehyde, it is an indispensable flavor for modulating daffodil and rose flavors. Cinnamyl alcohol is a food spice permitted in China's "Sanitary Standards for the Use of Food Additives". It is mainly used to prepare strawberry, lemon, apricot, peach and other fruit-type food flavors and brandy flavors. Second, organic synthesis intermediates Can be used to prepare cinnamyl chloride, which is an excellent raw material for the preparation of long-acting and multifunctional vasoconstriction antagonist cerebrolysin.At the same time, cinnamyl chloride can also be used to synthesize the anti-pathogenic microbial drug naftifine and antineoplastic drugs Torremiffin. Flunarizine dihydrochloride is a calcium antagonist and can also be synthesized with cinnamyl chloride. Cinnamyl alcohol is also used as a raw material for the preparation of the cinnamyl laurate.
Product name: Cinnamic Acid Synonyms: trans-Cinnamic acid; trans-3-Phenyl-2-propenoic acid; 3-Phenylpropenoic acid; Cinnamylic acid; 2-Propenoic acid, 3-phenyl-, (2E)-; 3-Phenylacrylic acid; 3-Phenylacrylic acid CAS NO.: 140-10-3 Melting point: 133 °C Boiling point: 300 °C Density: 1.248 Refractive index: 1.5049 Flash point: >230 °F Storage temp.: Store at RT. Solubility: 0.4g/l PH: 3-4 (0.4g/l, H2O, 20) Form: White Crystalline Powder Content: â?¥99% Packaging: 25kg kraft paper bag Storage method: pay attention to the fire source, especially to avoid sunlight, and store it in a cool place. Solubility: Soluble in ethanol, methanol, petroleum ether, chloroform, soluble in benzene, ether, acetone, glacial acetic acid, carbon disulfide and oil, insoluble in cold water. Cinnamic acid is an organic compound with the formula C6H5CH=CHCOOH. It is a white crystalline compound that is slightly soluble in water, and freely soluble in many organic solvents. Classified as an unsaturated carboxylic acid, it occurs naturally in a number of plants. It exists as both a cis and a trans isomer, although the latter is more common. Cinnamic acid is a central intermediate in the biosynthesis of myriad natural products include lignolsto lignin and lignocellulose, flavonoids, isoflavonoids, coumarins, aurones, stilbenes, catechin, and phenylpropanoids. Its biosynthesis is performed by action of the enzyme phenylalanine ammonia-lyase (PAL) on phenylalanine. Cinnamic acid is a precursor for the synthesis of a huge number of plant substances, including lignin, tannins, flavonoids, pigments, many of the flavor components of spices, and various alkaloids, such as morphine and colchicine. Usage: Cinnamic acid is an important substance because it is widely used in perfume, food, photographic, polymer and pharmaceutical industries, as well as for clinical and toxicological studies. Until now, many methods have been reported for its determination, such as titrimetry, differential-pulse polarography, spectrophotometry, mass spectrometry, HPLC, electrokinetic capillary chromatography, capillary electrophoresis, gas chromatography and liquid chromatography. However, there are many disadvantages over these methods, such as long-response time, reagent consumption, complicated operation, etc. 1. Flavors and fragrances 2. The pharmaceutical industry 3. Organic synthesis