Nomenclature:Common name dimethomorph (BSI, draft E-ISO); dime homorphe ((m) draft F-ISO)IUPAC name (E,Z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)acryloyl]morpholine Chemical Abstracts name (E,Z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl]morpholine CAS RN [110488-70-5] EEC no. 404-200-2 Development codes CME 151 (Celamerck); SAG 151; WL 127 294 (Shell); AC 336379; CL 183776; CL 336379 (all Cyanamid); BAS 550F Physical Chemistry:Composition (E)- to (Z)- ratio is c. 1:1. Mol. wt. 387.9 M.f. C21H22ClNO4 Form Colourless to off-white powder to crystals. M.p. 125.2-149.2 ; (E)- isomer 136.8-138.3 ; (Z)- isomer 166.3-168.5 V.p. (E)- isomer 9.7 ´ 10-4 ATXht981131 mPaATXht0 ; (Z)- isomer 1.0 ´ 10-3 ATXht981131 mPaATXht0 (both 25 ) KOW logP = 2.63 (E)- isomer; 2.73 (Z)- isomer (both 20 ) Henry (E)- isomer 5.4 ´ 10-6 Pa m3 mol-1; (Z)- isomer 2.5 ´ 10-5 Pa m3 mol-1 S.g./density Bulk density 1318 ATXht981107 kgATXht0 /m3 (20 ) Solubility In water 81.1 (ATXht981151 pHATXht0 5), 49.2 (ATXht981151 pHATXht0 7), 41.8 (ATXht981151 pHATXht0 9) (all in ATXht981123 mgATXht0 /l, 20). In n-heptane 0.12 (E), 0.053 (Z); xylene 22.2 (E), 6.4 (Z); 1,2-dichloroethane 182.5 (E), 92.5 (Z); ethyl acetate 46.6 (E), 9.5 (Z); acetone 105.6 (E), 18 (Z), methanol 33.5 (E), 7.5 (Z) (all in ATXht981123 mgATXht0 /l). In n-hexane 0.11, methanol 39, ethyl acetate 48.3, toluene 49.5, acetone 100, dichloromethane 461 (all for (EZ), in ATXht981123 mgATXht0 /l). Stability Hydrolytically and thermally stable under normal conditions. Stable for >5 years in the dark. The (E)- and (Z)- isomers are interconverted in sunlight. pKa -1.305 (ATXht98124 calc.ATXht0 ) F.p. Not flammable
Nomenclature:Common name tricyclazole (BSI, E-ISO, (m) F-ISO, ANSI) IUPAC name 5-methyl-1,2,4-triazolo[3,4-b][1,3]benzothiazole Chemical Abstracts name 5-methyl-1,2,4-triazolo[3,4-b]benzothiazole CAS RN [41814-78-2] EEC no. 255-559-5 Development codes EL-291 (Lilly) Physical Chemistry:Mol. wt. 189.2 M.f. C9H7N3S Form Crystalline solid. M.p. 184.6-187.2 B.p. 275 V.p. 5.86 ´ 10-4 ATXht981131 mPaATXht0 (20 , Knudsen-Effusion Weight Loss Method) KOW logP = 1.42 Henry 1.86 ´ 10-7 Pa m3 mol-1 (20 , TXht98124 calc.ATXht0 ) S.g./density 1.4 (20 ) Solubility In purified water 0.596 g/l (20 ). In acetone 13.8, methanol 26.5, xylene 4.9 (all in g/l, 20 ). Stability Stable at 52 (highest storage temperature tested). Relatively stable to ATXht981187 u.v.ATXht0 light
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