The cationic etherifying agent is a kind of application in the field of fine chemical products.Its chemical name is N- (3- chloro -2- hydroxypropyl) N, N, N three methyl ammonium chloride (CTA),molecular formula is C6H15NOCl2, formula weight is 188.1,The water solution at room temperature is 69%, and can be converted into the structure of epoxidation immediately under alkaline condition. CHPTAC 69% C6H15ONCl2 QUAT 188 has many names such as quat 188, CHPTAC, PTAC, CTA, Cationic Reagent, etc, used for cationic starch, cationic guar gum, cationic cellulose, cationizing reagent. Tiancheng is one of the world`s largest manufacturers of Alkyl Ketene Dimer (AKD Wax) with 20 years experiences and the largest and best manufacturer of cationic reagent (3-Chloro-2-Hydroxypropyltrimethyl Ammonium Chloride/quat 188/CHPTAC), raw material for producing cationic starch in China. Other featured products:General AKD Emulsifier 25%, Quat 188 69%,Polymer emulsifier 40%, PolyDADMAC 40%,Wet strenght agent 12.5%/25%, Styrene Acrylic Copolymer , Fixing Agent 50%, Poly Aluminium Chloride, Sodium Gluconate Oxidized Starch,ect.
Advantage:
The product appearance is transparent liquid, colorless and tasteless, the impurity content is low, is less than 10ppm.
Because the use of continuous production process, product quality is stability;
The product response rate is higher than 90%.
Application area
1) paper industry
Mainly as a liquid cationic etherifying agent, widely used in fiber, cellulose derivatives and starch modified; as paper internal application of adhesive, filler and fine fiber interception of additives.
(2) Water treatment industry
Suspended matters in water is negatively charged, react whit liquid cationic etherifying agent,produce cationic polymer as flocculants are widely used in water purification.
(3) chemical industry for daily use
The reaction of aqueous cationic etherifying agent create cationic guar gum are important chemicals.
Storage condition:
container must be built strictly, stored in a cool ventilated dry place.
AKD wax introduction
Chemical name: Alkyl Ketene Dimer
Alias: AKD wax
AKD powder is also called AKD wax. Chemical name is Alkyl ketene dimer. CAS registration number is 144245-85-2. Appearance is pale yellow flake or granular solid. It is produced by fatty acid (C16), via acylation and dehydrochlorination to become AKD wax. AKD wax is mainly used for papermaking neutral sizing agent. R or R' in the above structural formula is the alkyl group, and a series of alkyl ketene dimers can be obtained through modifying different alkyl groups. Octodecane and cetane are applicable to the papermaking neutral sizing agent.
Alkyl ketene dimer is a white-to-yellow solid with the melting point of about 47 ~ 51 , which can be soluble in ethyl alcohol, benzene, chloroform and other organic solvents. The reactive group of alkyl ketene dimer-ketone group has high activity
and makes esterification reaction with the hydroxyl in cellulose.
Product Application
AKD wax can be made into AKD emulsion applied as in sizing agent in the papermaking production.
AKD wax is emulsified by the cationic emulsifier, and melted AKD wax and emulsifier undergo high-speed shearing and high pressure homogenization to form the liquid AKD sizing agent after cooled.
In the papermaking process, application of AKD sizing agent gives the fluid resistance to paper and paperboard to prevent or delay the penetration and diffusion of some liquids on paper fibers, thus satisfying people's requirements on the processing and use of paper products.
AKD contains hydrophobic group and hydrophilic group, which are well distributed in the sizing process to transfer to locate the process of bonding with cellulose. AKD emulsion particles stay between negatively charged paper fibers since they carry with
positive charge by virtue of cationic starch and PAM and other retention agents; In the pressing and drying process of the paper machine, these globular AKD particles are easily expanded and distributed on the surface of fibers due to the lower melting point to form a homogeneous cover film; When paper is dried and stored for a period, the active group (lactone ring) on AKD molecule makes the esterification reaction with the hydroxyl on fibers under certain conditions to be binding on fibers in the form of fixed covalent bonds. Hydrophobic long-chain alkyls transfer to the paper surface in order to give the penetration resistance to paper.
Cationic reagent QUAT188 are aqueous solutions of monomer (3-chloro-2- hydroxypropyl) trimethylammonium chloride (CHPTAC). Cationic reagent are clear,odorless liquids.It is used to modify natural and syntheti polymers into quaternary ammonium compounds. It is used industrially for chemical processing of personal-care products, pulp and paper, textiles, and for water management.
Advantage:
The product appearance is transparent liquid, colorless and tasteless, the impurity content is low, is less than 10ppm.
Because the use of continuous production process, product quality is stability;
The product response rate is higher than 90%.
Application area
1) paper industry
Mainly as a liquid cationic reagent, widely used in fiber, cellulose derivatives and starch modified; as paper internal application of adhesive, filler and fine fiber interception of additives.
(2) water treatment industry
Suspended matters in water is negatively charged, react whit liquid cationic etherifying agent,produce cationic polymer as flocculants are widely used in water purification.
(3) chemical industry for daily use
The reaction of aqueous cationic etherifying agent create cationic guar gum are important chemicals.
Package :
250kg plastic drum , IBC drum , Flexitank
AKD wax(Alkyl Ketene Dimer, Simplified: AKD) is a neutral sizing agent, which can directly react with fiber. AKD wax produced by Shandong Tiancheng Chemical Co., Ltd, With high content and low acid value, is more efficient a sizing agent.
AKD WAX Advantage
1. Higher purity
2. Lower acid value
PRODUCT DESCRIPTION
AKD WAX Specification
Assay %: 90 min
Iodine Number gI2/100g: 45 min
Acid Value cPs/25â??: 5.0 max
Melting Point: 47 min
Appearance: Pale yellow granule
Packaging: 25kg/bag
Shelf life: 6 months
1. Product name:
AKD High Polymer Emulsifier
2. Product introduction:
AKD high polymer emulsifier (instead of traditional cationic starch based) is a kind of cationic polymer product developed by our technical department,which is the initiative developed product in the market.It can not only emulsify AKD wax,but also proteched the AKD colloid dispersion and aid retention,it also can increase AKD sizing efficiency(2%-8%).It can get the high stability and better fixing effect AKD emulsion by mechanical stirring,in the meantime it greatly decrease AKD hygrolysis during storage and sizing process.Final AKD Emulsion shelf time is about 6 months which is longer than starch emulsified AKD emulsion.The final AKD Emulsion also has quicker curing effect.
3.Specification and Index:
Item
Specification
Appearance
light yellow viscosity liquid
Solid content
40%min
Viscosity,mPa.s,25�°C
2000-10000 mPa.s
pH value
2-5
shelf life
6 months
4. Application:
This Emulsifier greatly restricts the AKD hydrolysis and the migration aptitude.It can replace the starch based emulsifier and AKD curing agent,at the same time decrease the AKD WAX using quantity.The final AKD Emulsion by this high polymer emulsifier can realize 80% sizing effect after paper machine,and almost totally realize after rewinding,which can let the paper immediately get the good water resistance effect,so less surface sizing agent in size press can fulfill all the sizing requirement.For detail using method,please contact Greatland Chemicals Co.,Ltd.
5. Package and storage:
It should be stored in the warehouse with dry and cool condition protected from frozen and sunlight directly. The temperature should be below 30 C.
Packing with 200kg, 1000kg/drum.
